New evidences of hydrothermal fluids circulation at the Devonian Kess Kess mounds,Hamar Laghdad (eastern Anti‐Atlas,Morocco)     

Fulvio Franchi  Barbara Cavalazzi  Catherine Pierre  Roberto Barbieri 《Geological Journal》2015,50(5):634-650

New evidences based on a combination of field and laboratory investigations reinforce the hypotheses that the circulation of warm fluids has remarkably contributed to the origin and development of the Devonian Kess Kess mounds of the Hamar Laghdad Ridge (eastern Anti‐Atlas, Morocco). The limestones of the Hamar Laghdad Ridge were deposited above a structural high generated by calc‐alkaline volcanic activity that has probably fuelled the circulation of warm fluids throughout the overlying carbonate units. The geological and palaeontological attributes described throughout the succession of the Hamar Laghdad Ridge (from the Lochkovian to Frasnian intervals) are interpreted as the result of hydrothermal processes related to a volcanic system. In particular, these attributes seem consistent with a chemo‐physical environment fuelled by the circulation of warm and late magmatic fluids. These attributes include a very low oxygen stable isotope signature (δ¹⁸O ~ −10‰) for carbonates. Evidences for a late magmatic fluid circulation consist of volcanic glass and pyroclasts replacement with hydrothermal minerals such as quartz, anatase and clinochlore. Fluids circulating through veins and pores into sediments, and venting to the seafloor, probably induced the formation of cavities where monospecific trilobite communities were detected. The partially silicified trilobite remains are associated with traces of goethite. This iron‐bearing oxide mineral is also present in the upper part of the Hamar Laghdad Ridge. All these attributes are here interpreted as possible evidences for a low‐temperature hydrothermal venting system active during the Lochkovian–Frasnian time span. This study combines an updated revision with new petrographic, geological and geochemical results aimed at providing an overall framework on the origin and early diagenesis of the Devonian succession of Hamar Laghdad. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Numerical models of ionic diffusion in one and three dimensions: application to dehydration of mantle olivine   总被引：1，自引：0，他引：1  

Catherine Thoraval  Sylvie Demouchy 《Physics and Chemistry of Minerals》2014,41(9):709-723

The hydrogen content of nominally anhydrous minerals is of great interest, because it can influence many physical and mechanical properties of mantle rocks. Moreover, the hydrogen diffusion profiles can be used to constrain timescales related to magma eruptions. Here, we report models of ionic diffusion for trace elements in anisotropic crystals and apply them to hydrogen diffusing out of mantle-derived olivine. We first compare and discuss the characteristics of 1D and 3D models and show that only 3D anisotropic diffusion models can lead to diffusion profiles exhibiting non-equilibrium plateau at the center of the solid along the slowest axis, as measured in natural samples. In a second part, we discuss the differences between hydration and dehydration of olivine for diffusion that is linked to two different atomic sites involved in hydrogen mobility. Finally, we apply our 3D anisotropic model to previous results on mantle-derived olivine from Pali-aike to better characterize diffusion coefficients and their anisotropy that could be relevant for dehydration of olivine. Our results show that dehydration has to be strongly anisotropic, with a fast [100] axis and a significantly slower [001] axis.  相似文献   

Economics of climate policy and collective decision making   总被引：1，自引：0，他引：1  

Beat Bürgenmeier  Andrea Baranzini  Catherine Ferrier  Céline Germond-Duret  Karin Ingold  Sylvain Perret  Peter Rafaj  Socrates Kypreos  Alexander Wokaun 《Climatic change》2006,79(1-2):143-162

This paper explores the reasons why economic instruments of climate change are reluctantly applied and stresses the need for interdisciplinary research linking economic theory and empirical testing to deliberative political procedures. It is divided in three parts. The first one recalls the main issues in implementing Cost-Benefit Analysis such as information problems, uncertainties, discounting the future and irreversibilities. The second part shows how these issues can be treated in integrated assessment and techno-economic models and presents a case study, which shows that

• The chosen scenario tends to stabilize atmospheric CO₂ concentration at around 550 ppm in the long run.
• Exclusion of possibility to trade CO₂ emission permits under a cap regime would increase the cost of emission abatement for OECD countries.
• Combining different flexibility instruments might lead to significant gains in the overall cost of climate policy.

The third part presents results of a survey conducted among the main economic and environmental associations in Switzerland. The survey reveals conflicting views on economic instruments. It shows how the social acceptability of these instruments can be improved in taking explicitly into account these opposing views of special interest groups. Therefore, policy scenarios should be selected in combining techno-economic models with empirical studies about their political and normative context.  相似文献   

Polychlorinated biphenyls and DDT residues distribution in sediments of Cortiou (Marseille, France)   总被引：1，自引：0，他引：1  

Wafo E  Sarrazin L  Diana C  Schembri T  Lagadec V  Monod JL 《Marine pollution bulletin》2006,52(1):104-107

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Stabilization of Fe/Cu nanoparticles by starch and efficiency of arsenic adsorption from aqueous solutions     

Yassaman Babaee  Catherine N. Mulligan  Md. Saifur Rahaman 《Environmental Earth Sciences》2017,76(19):650

Due to the severity of arsenic contamination of soil and water resources around the world, finding new adsorbents for arsenic removal from the water is of high importance. The present study investigates the possible use and effectiveness of starch-stabilized Fe/Cu nanoparticles for adsorption of arsenic from aqueous solutions. First, Fe/Cu nanoparticles at various starch concentrations of 0, 0.02, 0.04 and 0.06 wt% were synthesized and characterized by X-ray diffraction, transmission electron microscopy and zeta potential/particle size analyzer. Then 0.04 wt% stabilized Fe/Cu nanoparticles were tested for the sorption of As(III) and As(V) from synthetic arsenic-contaminated water. To have an understanding about the arsenic adsorption mechanism of nanoparticles, X-ray photoelectron spectroscopy (XPS) was performed before and after adsorption. The results showed that starch provides nanoparticles with a neutral surface and stabilization of nanoparticles is possible with 0.04 wt% or higher concentrations of starch. For 0.04 wt% starch-stabilized Fe/Cu nanoparticles, the adsorption isotherms fit well within the Langmuir equation, with maximum sorption capacities of 90.1 mg/g for As(III) and 126.58 mg/g for As(V) at a pH of 7.0 from the aqueous arsenic solutions. Examining the XPS spectra of nanoparticles before and after adsorption showed that arsenic adsorption by this nanoparticle can be due to the formation of inner-sphere arsenic complexes on the particle surface, and the surface oxygen-containing functional groups involved in adsorption. The high sorption capacity suggests the potential for applying starch-stabilized Fe/Cu nanoparticles to the contaminated waters for removal of arsenic.  相似文献   

Evaluating qualitative research: dealing with the tension between 'science' and 'creativity'   总被引：1，自引：0，他引：1  

Cathy Bailey  Catherine White  Rachel Pain 《Area》1999,31(2):169-178

Summary This paper responds to recent calls for detailed evaluative criteria for qualitative research in human geography. It argues that the dualism between 'science' and 'creativity' is unfounded, and that while systematic methods of evaluation are required, standardization is inappropriate. Furthermore, it seeks to demonstrate that grounded theory provides an alternative framework that demonstrates how these ideas might be put into practice.  相似文献   

Ascent and eruption of a lunar high-titanium magma as inferred from the petrology of the 74001/2 drill core     

Catherine M. WEITZ  Malcolm J. RUTHERFORD  James W. HEAD III  David S. McKAY 《Meteoritics & planetary science》1999,34(4):527-540

Abstract— An analysis of the orange glasses and crystallized beads from the 68 cm deep 74001/2 core has been conducted to understand the processes occurring during ascent and eruption of the Apollo 17 orange glass magma. Equilibrium between melt and metal blebs (Fe₈₅Ni₁₄Co₁) within the core, along with Cr contents in olivine phenocrysts, suggest there was an oxidation of C and a reduction of the melt at an O fugacity of IW-1.3 and 1320 °C to form CO gas at 200 bars or ～4 km depth. This was followed by development of more oxidized conditions during ascent. Also during ascent, there was formation of euhedral, homogeneous Fo₈₁ olivine crystals and spinel crystals with higher Al and Mg contents than the smaller spinels in the crystallized beads. Both the metal blebs and Al-rich spinels were trapped inside the Fo₈₁ olivine phenocrysts as they grew prior to eruption. The composition of the orange glasses are homogeneous throughout the core, except for a few distinct glasses at the top that appear to have been mixed in by micrometeorite reworking. A few glassy melt inclusions of orange glass composition trapped in the Fo₈₁ phenocrysts contain 600 ± 100 ppm S and ～50 ppm Cl compared to the 200 ppm S and 50 ppm Cl in the orange glass melt when quenched. These inclusions therefore document the addition of 400 ppm S to the CO-rich volcanic gas during the eruption. The size and distribution of different volcanic beads in the Apollo 17 deposit indicate a mode of eruption in which the orange glasses and partially crystallized beads formed further away from the volcanic vent where cooling rates were faster. Progressively larger and more numerous crystals in the black beads reflect slower cooling rates at higher optical densities in the volcanic plume. The development of a brown texture in the orange glasses at the bottom of the core, where the black beads dominate, is interpreted to result from devitrification by subsolidus heating either as the orange glasses fell back through the hot plume or after deposition on the surface. The change from domination by orange glasses to black beads in the core probably reflects a decrease in gas content over time, which consequently would increase the plume optical density and favor slower cooling rates.  相似文献   

Extension et sédimentation au paléozoïque terminal et au Mésozoïque dans le bassin de Majunga (Nord-Ouest de Madagascar)     

Yolande Razafindrazaka  Thogne Randriamananjara  Alain Piqu  Catherine Thouin  Edgard Laville  Jacques Malod  Jean-Pierre Rhault 《Journal of African Earth Sciences》1999,28(4):949-959

The Majunga Basin is located in the northwestern part of Madagascar with a N45–60°E trending axis. It was filled by almost exclusively continental Karoo Supergroup sediments, which are Permian to Early Jurassic in age, and by younger sequences, mainly marine, that were deposited from the Middle Jurassic to the present.The Karoo Basin geometry is deduced from the analysis of seismic sections. A central northeast trending horst is flanked by two sub-basins. Deposition of the Karoo sequences was controlled by these northeast trending faults. On the contrary, the Middle Jurassic to present sequences witness only a slight tilting of the basement towards the northwest.The development of the Majunga Basin includes, therefore, two successive stages. In the synrift episode, from Permian to Early Jurassic times, the sedimentation was syntectonic, controlled by synsedimentary faulting and the creation of a horst and graben extensive pattern. The postrift episode started during the Middle Jurassic.These two stages of the Majunga Basin development correspond to the geodynamic evolution recorded elsewhere in this part of the Gondwana.  相似文献   

An automated cross‐validation method to assess seismic time‐to‐depth conversion accuracy: a case study on the Cooper and Eromanga basins,Australia          下载免费PDF全文

David Kulikowski  Catherine Hochwald  Khalid Amrouch 《Geophysical Prospecting》2018,66(8):1521-1534

Selecting a seismic time‐to‐depth conversion method can be a subjective choice that is made by geophysicists, and is particularly difficult if the accuracy of these methods is unknown. This study presents an automated statistical approach for assessing seismic time‐to‐depth conversion accuracy by integrating the cross‐validation method with four commonly used seismic time‐to‐depth conversion methods. To showcase this automated approach, we use a regional dataset from the Cooper and Eromanga basins, Australia, consisting of 13 three‐dimensional (3D) seismic surveys, 73 two‐way‐time surface grids and 729 wells. Approximately 10,000 error values (predicted depth vs. measured well depth) and associated variables were calculated. The average velocity method was the most accurate overall (7.6 m mean error); however, the most accurate method and the expected error changed by several metres depending on the combination and value of the most significant variables. Cluster analysis tested the significance of the associated variables to find that the seismic survey location (potentially related to local geology (i.e. sedimentology, structural geology, cementation, pore pressure, etc.), processing workflow, or seismic vintage), formation (potentially associated with reduced signal‐to‐noise with increasing depth or the changes in lithology), distance to the nearest well control, and the spatial location of the predicted well relative to the existing well data envelope had the largest impact on accuracy. Importantly, the effect of these significant variables on accuracy were found to be more important than choosing between the four methods, highlighting the importance of better understanding seismic time‐to‐depth conversions, which can be achieved by applying this automated cross‐validation method.  相似文献   

SSIIM: Sediment simulation in intakes with multiblock option. A model for free surface flows     

Catherine A.M.E Wilson 《水文研究》2000,14(14):2619-2622

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